Tetraaquabis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN 2}manganese(II) dihydrate
نویسنده
چکیده
The title compound, [Mn(C(4)H(3)N(8))(2)(H(2)O)(4)]·2H(2)O, represents the first structurally characterized transition metal complex of the 1,2-bis-(tetra-zol-5-yl)ethene ligand. The complex mol-ecule occupies a special position on an inversion centre and the Mn atom has a tetra-gonally distorted octa-hedral coordination. The bis-(tetra-zolyl)ethene ligand is planar within 0.0366 (7) Å. All 'active' H atoms participate in hydrogen bonds, which link mol-ecules of the complex and the uncoordinated water mol-ecules into an infinite three-dimensional framework.
منابع مشابه
Tetraaquabis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN 2}manganese(II) dihydrate. Corrigendum
The chemical name in the title of the paper by Hu [Acta Cryst. (2008), E64, m772] is corrected.[This corrects the article DOI: 10.1107/S1600536808012464.].
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